{"id":7435,"date":"2024-01-01T07:57:48","date_gmt":"2024-01-01T04:27:48","guid":{"rendered":"https:\/\/myepanel.ir\/farapol\/en\/?p=7435"},"modified":"2025-01-25T11:10:05","modified_gmt":"2025-01-25T07:40:05","slug":"article2","status":"publish","type":"post","link":"https:\/\/farapol.com\/en\/article2\/","title":{"rendered":"Simultaneous  electrochemical  detection of antioxidants Hydroquinone, Mono-Tert-butyl hydroquinone and catechol in food and polymer samples using ZnO@MnO2-rGO nanocomposite as sensing layer"},"content":{"rendered":"<section class=\"l-section wpb_row height_medium\"><div class=\"l-section-h i-cf\"><div class=\"g-cols vc_row via_flex valign_top type_default stacking_default\"><div class=\"vc_col-sm-6 wpb_column vc_column_container\"><div class=\"vc_column-inner us_custom_9cf479d2 type_sticky\"><div class=\"wpb_wrapper\"><div class=\"w-post-elm post_image stretched\"><img loading=\"lazy\" decoding=\"async\" width=\"490\" height=\"266\" src=\"https:\/\/farapol.com\/en\/wp-content\/uploads\/2024\/01\/1.png\" class=\"attachment-full size-full wp-post-image\" alt=\"\" srcset=\"https:\/\/farapol.com\/en\/wp-content\/uploads\/2024\/01\/1.png 490w, https:\/\/farapol.com\/en\/wp-content\/uploads\/2024\/01\/1-300x163.png 300w\" sizes=\"(max-width: 490px) 100vw, 490px\" \/><\/div><\/div><\/div><\/div><div class=\"vc_col-sm-6 wpb_column vc_column_container\"><div class=\"vc_column-inner\"><div class=\"wpb_wrapper\"><h2 class=\"w-post-elm post_title us_custom_c4648a83 align_left entry-title color_link_inherit\">Simultaneous  electrochemical  detection of antioxidants Hydroquinone, Mono-Tert-butyl hydroquinone and catechol in food and polymer samples using ZnO@MnO2-rGO nanocomposite as sensing layer<\/h2><div class=\"w-hwrapper us_custom_8b86dc01 valign_middle align_justify\"><div class=\"w-text\"><span class=\"w-text-h\"><span class=\"w-text-value\">Share this article:<\/span><\/span><\/div><div class=\"w-sharing type_simple align_none color_default\"><div class=\"w-sharing-list\"><a class=\"w-sharing-item facebook\" href=\"https:\/\/www.facebook.com\/sharer\/sharer.php?u=https:\/\/farapol.com\/en\/wp-json\/wp\/v2\/posts\/7435&amp;quote=Simultaneous  electrochemical  detection of antioxidants Hydroquinone, Mono-Tert-butyl hydroquinone and catechol in food and polymer samples using ZnO@MnO2-rGO nanocomposite as sensing layer\" title=\"Share this\" aria-label=\"Share this\" onclick=\"window.open(this.href, &quot;facebook&quot;, &quot;toolbar=0,width=900,height=500&quot;); 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return false;\"><i class=\"fab fa-telegram\"><\/i><\/a><\/div><div class=\"w-sharing-tooltip active\" style=\"display:none\" data-sharing-area=\"l-main\"><div  class=\"w-sharing-list\" data-sharing-url=\"https:\/\/farapol.com\/en\/wp-json\/wp\/v2\/posts\/7435\"><a  class=\"w-sharing-item facebook\" title=\"Share this\" aria-label=\"Share this\" onclick=\"window.open(this.href, &quot;facebook&quot;, &quot;toolbar=0,width=900,height=500&quot;); return false;\" data-url=\"https:\/\/www.facebook.com\/sharer\/sharer.php?u=https:\/\/farapol.com\/en\/wp-json\/wp\/v2\/posts\/7435&amp;quote={{text}}\"><i class=\"fab fa-facebook\"><\/i><\/a><a  class=\"w-sharing-item whatsapp\" title=\"Share this\" aria-label=\"Share this\" onclick=\"window.open(this.href, &quot;whatsapp&quot;, &quot;toolbar=0,width=900,height=500&quot;); return false;\" data-url=\"https:\/\/web.whatsapp.com\/send?text={{text}} https:\/\/farapol.com\/en\/wp-json\/wp\/v2\/posts\/7435\"><i class=\"fab fa-whatsapp\"><\/i><\/a><a  class=\"w-sharing-item telegram\" title=\"Share this\" aria-label=\"Share this\" onclick=\"window.open(this.href, &quot;telegram&quot;, &quot;toolbar=no,width=600,height=450&quot;); return false;\" data-url=\"https:\/\/t.me\/share\/url?url=https:\/\/farapol.com\/en\/wp-json\/wp\/v2\/posts\/7435&amp;text={{text}}\"><i class=\"fab fa-telegram\"><\/i><\/a><button class=\"w-sharing-item copy2clipboard\" title=\"Copy\" aria-label=\"Copy\"><i class=\"fas fa-copy\"><\/i><\/button><\/div><\/div><\/div><\/div><div class=\"w-separator size_small\"><\/div><div class=\"wpb_text_column us_custom_e4bc1fd0\"><div class=\"wpb_wrapper\"><p style=\"text-align: left;\"><strong>The contemporaneous monitoring\u00a0 of the isomers of molecules is a severe challenge\u00a0 in analytical \u00a0chemistry because of their similar phys- ical, chemical, \u00a0and electrochemical properties. For this reason, it is vital to develop a simple, selective, and sensitive method for monitoring them simultaneously.<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>HQ, \u00a0MTBHQ, \u00a0and CC are three isomers of phenolic compounds, that are applied in industrial production of cosmetics,\u00a0 coal-tar production, pharmaceuticals,\u00a0 tanning, pesticides, flavouring agents, polymerization inhibitor and antioxidants,\u00a0 paper manufacturing, \u00a0chemicals dyes, reducing agent, food and photography and photo stabilizer (Hassan, Hathoot, \u00a0Abo oura, &amp; Azzem, \u00a02018; Ishack &amp; Lipner, 2022; Sebastian, Yu, Balram, Al-Mubaddel, \u00a0&amp; Noman, \u00a02022).<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>Also, \u00a0these compounds \u00a0are used in \u00a0polymer \u00a0industries because of<\/strong><\/p>\n<p style=\"text-align: left;\"><strong>their \u00a0excellent \u00a0antioxidant \u00a0features, \u00a0chemical \u00a0stability, \u00a0cost-effective<\/strong><\/p>\n<\/div><\/div><\/div><\/div><\/div><\/div><\/div><\/section><section class=\"l-section wpb_row us_custom_887a049b height_medium\"><div class=\"l-section-h i-cf\"><div class=\"g-cols vc_row via_flex valign_top type_default stacking_default\"><div class=\"vc_col-sm-12 wpb_column vc_column_container\"><div class=\"vc_column-inner\"><div class=\"wpb_wrapper\"><div class=\"wpb_text_column\"><div class=\"wpb_wrapper\"><p><strong>Based on the previous reports, some nanomaterials can improve resolution between peaks so the simultaneous determination of analytes with the same peak potential can be made possible. Additionally, these nanomaterials can improve the LR and LOD of electrochemical sensors.<\/strong><\/p>\n<p><strong>The \u00a0surface \u00a0properties \u00a0of \u00a0nanomaterials \u00a0including\u00a0 \u00a0surface \u00a0area,<\/strong><\/p>\n<p><strong>roughness \u00a0(as \u00a0reaction\u00a0 \u00a0sites), \u00a0electron\u00a0\u00a0 distributions,\u00a0 \u00a0electrical\u00a0 \u00a0and thermal conductivity, and energetics make nanomaterials a suitable candidate for use in electrochemical \u00a0sensors because they can enhance electron transfer and interactions of the electrode surface and analytes (Bagheri, Shirzadmehr, Rezaei, &amp; Khoshsafar, 2018; Karimi-Maleh et al.,<\/strong><\/p>\n<p><strong>2022; Rezaei, \u00a02016; Zeinali, \u00a0Khoshsafar, Rezaei, \u00a0&amp; Bagheri, 2018).<\/strong><\/p>\n<p><strong>Due to the wide variety and especial features,\u00a0 carbon-based nano- particles \u00a0(CBN) \u00a0have \u00a0been\u00a0 used broadly \u00a0in \u00a0chemistry. \u00a0A \u00a0comparison between carbon atoms in the plane and edges in CBN\u00a0 shows that the reactivity of the edges of carbon atoms is more than at the plane. One of the \u00a0ways \u00a0to \u00a0boost\u00a0 the \u00a0chemical \u00a0and \u00a0physical \u00a0properties of \u00a0CBN \u00a0and achieve new properties is to merge these materials with other NPs such as Metal NPs and Metal oxide NPs (Kant et al., \u00a02022).<\/strong><\/p>\n<p><strong>ZnO NPs is an <em>n<\/em>-type metal oxide semiconductors with high chemical<\/strong><\/p>\n<p><strong>stability. \u00a0In addition \u00a0to ZnO\u2019s high \u00a0isoelectric\u00a0 point, \u00a0acceptable \u00a0elec- trochemical\u00a0\u00a0 characteristics \u00a0(electrical \u00a0conductivity\u00a0 \u00a0~\u00a0 \u00a0230 \u00a0S \u00a0cm\u00a0 \u00a01), simple and inexpensive synthesis process, and nontoxicity, \u00a0which make<\/strong><\/p>\n<p><strong>it\u00a0 an ideal \u00a0semiconductor \u00a0material \u00a0for a wide\u00a0 variety \u00a0of \u00a0applications (Kalpana &amp; Devi Rajeswari, \u00a02018). ZnO \u00a0NPs can provide efficient\u00a0 me- chanical \u00a0support and an electron-conducting \u00a0pathway\u00a0 for the Manga- nese dioxide (MnO2) NPs deposited layer because of their chemical stability, \u00a0mechanical \u00a0flexibility,\u00a0 \u00a0and \u00a0conductivity.\u00a0 \u00a0Owing \u00a0to \u00a0its \u00a0high<\/strong><\/p>\n<p><strong>specific \u00a0capacitance \u00a0(1370 \u00a0F \u00a0g\u00a0 \u00a01), \u00a0low \u00a0cost, \u00a0high \u00a0specific \u00a0area, \u00a0high<\/strong><\/p>\n<p><strong>isoelectric point,\u00a0 natural abundance, \u00a0and environmental compatibility with good electrochemical\u00a0 activity, \u00a0MnO2 \u00a0NPs (p-type semiconductor; Narrow bandgap ~ 1.44 eV) is one of the most talented transition metal oxides \u00a0for\u00a0 use in \u00a0the \u00a0electrical \u00a0instruments and \u00a0especially \u00a0for use in electrochemical sensors (Xiaona Li, Jiang, Li, Li, &amp; Li, 2022).<\/strong><\/p>\n<p><strong>Since clinical\u00a0 analysis in a clinical\u00a0 laboratory with huge analytical instruments is costly and an exhausting process and it is also not possible to measure the analytes on-site, analytical chemistry scientists are trying to invent new methods with miniaturization\u00a0 and portability ability. \u00a0As well as being sensitive and accurate, \u00a0the methods must be capable\u00a0 of<\/strong><\/p>\n<\/div><\/div><div class=\"w-btn-wrapper align_justify\"><a class=\"w-btn us-btn-style_2 us_custom_061ea1cf has_text_color icon_atleft\" href=\"https:\/\/farapol.com\/en\/wp-content\/uploads\/2025\/01\/16-Simultaneouselectrochemicaldetectionofanti.pdf\"><i class=\"fas fa-download\"><\/i><span class=\"w-btn-label\">Download The Article<\/span><\/a><\/div><\/div><\/div><\/div><\/div><\/div><\/section><section class=\"l-section wpb_row us_custom_0d15be52 height_medium\"><div class=\"l-section-h i-cf\"><div class=\"g-cols vc_row via_flex valign_top type_default stacking_default\"><div class=\"vc_col-sm-12 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